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磁场中浆料粘度与内部结构的关系研究

彭晓领 , 严密 , 罗伟 , 马天宇

无机材料学报 doi:10.3724/SP.J.1077.2008.00836

当外磁场施加在由铁磁性Ni和非磁性ZrO2粒子组成的浆料时, 浆料的粘度会明显增大. 实验采用磁场线圈、旋转粘度计和金相显微镜对磁场中Ni/ZrO2复合浆料的粘度与内部结构的关系进行了系统研究. 结果表明, 浆料粘度随着磁场强度和Ni含量的增加而增大. 当外磁场作用于浆料时, 浆料中会形成链状Ni团簇. 随着磁场强度的增加, Ni团簇尺寸变大, 阻碍了粒子的自由运动, 因此粘度增加. 同样, 随着Ni含量的增大, 浆料中Ni团簇增多, 因此粘度增大.

关键词: 粘度 , magnetic particle , chain-like cluster , magnetic field , FGM

镍源对自蔓延高温合成Ni0.35Zn0.65Fe2O4的影响

王建华 , 刘玉存 , 刘登程 , 郭豪

无机材料学报 doi:10.3724/SP.J.1077.2009.00973

在空气中(无磁场)和1.3T外磁场下, 采用Fe、Fe2O3、ZnO、NaClO4分别与Ni粉、NiO和NiCO3进行了自蔓延高温合成Ni0.35Zn0.65Fe2O4的实验研究, 用红外测温仪测试坯料的燃烧温度, 应用XRD、SEM和VSM分别观察镍源变化对燃烧产物和烧结后样品性能的影响. 结果表明:采用氧化亚镍和镍粉得到的镍锌铁氧体样品无杂相存在, 磁性能较好, 有较低的矫顽力和较大的比饱和磁化强度; 采用碳酸镍自蔓延高温合成的镍锌铁氧体含有杂相, 磁性能也相应较差. 在外磁场下自蔓延高温合成镍锌铁氧体的比饱和磁化强度得到了一定的提高. 镍粉可以取代氧化亚镍作为自蔓延高温合成镍锌铁氧体的镍源.

关键词: 镍锌铁氧体 , self-propagating high-temperature synthesis , magnetic field , magnetic performance

电渣重熔体系内磁场的数学模拟

魏季和 , 任永莉

金属学报

基于Maxwell方程组及有关的电磁场理论,提出了更切合实际情况的电渣重熔体系内磁场的数学模型,并应用于结晶器直径200mm的实验室重熔装置.对直径76mm低碳低合金钢电极的重熔过程(3000A(有效值),CaF2+30mass%Al2O3+20mass%CaO渣系),结果表明,磁场强度的幅模在电极内沿端部锥体形成方向不断增大,至接近锥顶处达最大值,约为2.6×104A/m,此后在渣池、锭子熔池、液固两相区和固态锭子内沿轴向向下逐渐减小;沿半径方向,在电极和渣池内呈现一峰值,在液、固金属区内则单调增大至边界条件限定值.对在直径140mm的结晶器中以直径80mm的电极和CaF2+CaO+Al2O3+MgO渣系生产高速钢(M2)锭的过程,以该模型估计的重熔体系渣池和金属熔池内磁场强度(幅模)的大小和分布与实测结果较相吻合.该模型可作为研究电渣重熔体系内熔体流动,传热和传质过程的基础.

关键词: 电渣重熔 , magnetic field , mathematic simulation , null

磁场对Cu-Pb-La过偏晶合金液-液分离的作用

张林 , 王恩刚 , 左小伟 , 赫冀成

稀有金属

本实验在Cu-80%Pb过偏晶合金凝固过程中添加稀土元素La,研究不同冷却速度下稀土元素在过偏晶合金凝固制备中的作用,并研究施加磁场对Cu-Pb过偏晶合金液-液分离区凝固组织的影响,探讨了磁场下第二相的迁移和分布规律,为均质偏晶合金制备技术的改进提供参考.结果表明,添加La元素可显著降低Cu-80%Pb凝固组织中的宏观偏析,促进第二相颗粒的均匀分布和细化.较快的冷却速度下添加La元素的作用更加明显,偏析程度显著降低,在此冷速下进一步施加1T水平方向磁场,Cu-Pb-La合金凝固过程中宏观偏析得到了抑制,富Cu相颗粒弥散,组织分布均匀.

关键词: Cu-Pb-La , 过偏晶合金 , 磁场 , 液-液分离

磁场辅助激光沉积修复钛合金的组织和性能

钦兰云 , 杨光 , 卞宏友 , 王维 , 任宇航 , 刘奇

稀有金属材料与工程

为了调控激光沉积修复BT20钛合金的组织,提高其力学性能,将旋转磁场引入到激光修复系统中,考察了不同磁场强度下修复试样的组织和力学性能.结果显示,修复区和基体形成了致密冶金结合,修复区为α/β片层组织,硬度分布从基材到修复区依次提高;在一定范围内,磁场强度越强,α片层长/径比越小,片层组织越细密,修复区硬度越大,HV0.1可达4.4 GPa.表明磁场搅拌减轻了β晶溶质富集,使α片层析出的驱动力减小,需要在更大过冷度下析出,而过冷度的增加,导致形核率的增大,最终导致α层片细化,从而提高沉积层的力学性能.

关键词: 钛合金 , 磁场 , 激光沉积修复 , 微观组织

ENERGY STORAGE IN METAl DEVICES AND THE ADVANTAGES OF LIQUID HYDROGEN TEMPERATURES

VR. SobolO.N MazurenkoA.A. Drozd and B.B. Boiko(Institute of Solid State and Semiconductor Physics ASB , P. Brovka Str. , 17 , 220072 Minsk , Belarus)

金属学报(英文版)

Peculiarities of low temperature charge transport and enerpy accumulation in alu-minum devices are investigated by means of study of cylindrical conductors having a rudial cuerent fiow between inner and outer concentric contracts. Azimuthal current and, connected with it, self magnetic field are investigated in a wide range of radial current density up to 6000 A/cm2 under an external magnetic field up to 8 T Electron scattering processes are investigated and it is shown that relaxation electron mechanisms are determined by strong temperature dependence on account of high sus-ceptibility of scattering to anisotropy of electron dispersion law. The role of thermal phonons is investigated through an effective averaged conductivity tensor of polycrystalline medium. Using data of self magnetic self distribution on sample surface an energy density of self magnetic field is estimated. It is shown that at T=4.2 K average energy of self field may achieve at least 1 J/cm3. Using data of relaxation processes at temperature of liquid hydrogen it is established that self magnetic field must be a third of helium magnitude with respective self magnetic enengy density, spiral motion of carriers in this geometry being regarded as a current coils in usual inductive element.

关键词: energy storage , null , null , null

DISTRIBUTION OF THE MAGNETIC FIELD AND ITS CONTROL EFFECT ON THE MOLTEN METAL FLOW IN FLOW CONTROL MOLD

G.J. Xu and J.C. He (The Key Laboratory of National Education Ministry for Electromagnetic Processing of Materials , Northeastern University , Shenyang 110006 , China)

金属学报(英文版)

A thermo-simulation experimental continuous caster was established to study the effect of two static magnetic fields imposed the whole width of the mold on the molten metal flow. Low melting point Bi-Pb-Sn alloy and silicon oil were adopted to simulate the molten metal and mold powder respectively. The results show that the control effect of electromagnetic fields on the molten metal flow in the different zones of mold is different. Therefore it is important to study and design new types of magnetic fields to satisfy the request of controlling the molten metal flow in the mold.

关键词: continuous casting mold , null , null

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